Characteristics of MSW and heat energy recovery between residential and commercial areas in Seoul

This paper analyzes the amount and characteristics of municipal solid waste (MSW) according to the inhabitant density of population and the business concentration in 25 districts in Seoul. Further, the heat energy recovery and avoided CO₂ emissions of four incineration plants located in residential and commercial areas in Seoul are examined. The amount of residential waste per capita tended to increase as the density of inhabitants decreased. The amount of commercial waste per capita tended to increase as the business concentration increased. The examination of the heat energy recovery characteristics indicated that the four incineration plants produced heat energy that depended on residential or commercial areas based on population and business. The most important result regarding avoided CO₂ emissions was that commercial areas with many office-type businesses had the most effective CO₂ emission savings by combusting 1 kg of waste. Assuming the full-scale operation of the four incineration plants, the amount of saved CO₂ emissions per year was 444 Gg CO₂ and 57,006 households in Seoul can be provided with heat energy equivalent to 542,711 Nm³ of LNG.     

Industrial experience of process identification and set-point decision algorithm in a full-scale treatment plant

This paper presents industrial experience of process identification, monitoring, and control in a full-scale wastewater treatment plant. The objectives of this study were (1) to apply and compare different process-identification methods of proportional-integral-derivative (PID) autotuning for stable dissolved oxygen (DO) control, (2) to implement a process monitoring method that estimates the respiration rate simultaneously during the process-identification step, and (3) to propose a simple set-point decision algorithm for determining the appropriate set point of the DO controller for optimal operation of the aeration basin. The proposed method was evaluated in the industrial wastewater treatment facility of an iron- and steel-making plant. Among the process-identification methods, the control signal of the controller's set-point change was best for identifying low-frequency information and enhancing the robustness to low-frequency disturbances. Combined automatic control and set-point decision method reduced the total electricity consumption by 5% and the electricity cost by 15% compared to the fixed gain PID controller, when considering only the surface aerators. Moreover, as a result of improved control performance, the fluctuation of effluent quality decreased and overall effluent water quality was better.     

Morphological and chemical composition characteristics of summertime atmospheric particles collected at Tokchok Island,Korea

Determination of the chemical compositions of atmospheric single particles in the Yellow Sea region is critical for evaluating the environmental impact caused by air pollutants emitted from mainland China and the Korean peninsula. After ambient aerosol particles were collected by the Dekati PM10 cascade impactor on July 17–23, 2007 at Tokchok Island (approximately 50 km west of the Korean coast nearby Seoul), Korea, overall 2000 particles (on stage 2 and 3 with cut-off diameters of 2.5–10 μm and 1.0–2.5 μm, respectively) in 10 samples were determined by using low-Z particle electron probe X-ray microanalysis. X-ray spectral and secondary electron image (SEI) data showed that soil-derived and sea-salt particles which had reacted or were mixed with SO₂ and NO_x (or their acidic products) outnumbered the primary and “genuine” ones (59.2% vs. 19.2% in the stage 2 fraction and 41.3% vs. 9.9% in the stage 3 fraction). Moreover, particles containing nitrate in the secondary soil-derived species greatly outnumbered those containing sulfate. Organic particles, mainly consisting of marine biogenic species, were more abundant in the stage 2 fraction than in the stage 3 fraction (11.6% vs. 5.1%). Their relative abundance was greater than the sum of carbon-rich, K-containing, Fe-containing, and fly ash particles, which exhibited low frequencies in all the samples. In addition, many droplets rich in C, N, O, and S were observed. They tended to be small, exhibiting a dark round shape on SEI, and generally included 8–20 at.% C, 0–12 at.% N, 60–80 at.% O, and 4–10 at.% S (sometimes with <3 at.% Mg and Na). They were attributed to be a mixture of carbonaceous matter, H₂SO₄, and NH₄HSO₄/(NH₄)₂SO₄, mostly from the reaction of atmospheric SO₂ with NH₃ under high relative humidity. The analysis of the relationship between the aerosol particle compositions and 72-h backward air-mass trajectories suggests that ambient aerosols at Tokchok Island are strongly affected not only by seawater from the Yellow Sea but also by anthropogenic pollutants emitted from China and the Seoul–Incheon metropolis, resulting in the dominance of complex secondary aerosol particles.     

Hydrogen-rich fuel gas production from refuse plastic fuel pyrolysis and steam gasification

In this study, experimental conditions were optimized to maximize the production of hydrogen gas from refuse plastic fuel (RPF) by pyrolysis and steam gasification processes conducted in a laboratory-scale reactor. We carried out gasification using 10-g RPF samples at different temperatures (700°-1000°C) with and without steam. The effect of the amount of steam (0–0.25 g/min) for RPF steam gasification was also studied. The effect of K₂CO₃ as a catalyst on these processes was also investigated. Experimental results showed that the hydrogen gas yield increased with temperature; with respect to the gas composition, the hydrogen content increased mainly at the expense of other gaseous compounds, which highlights the major extension of secondary cracking reactions in the gaseous fraction at higher temperatures.     

Development of a SWAT Patch for Better Estimation of Sediment Yield in Steep Sloping Watersheds1

Abstract: The watershed scale Soil and Water Assessment Tool (SWAT) model divides watersheds into smaller subwatersheds for simulation of rainfall‐runoff and sediment loading at the field level and routing through stream networks. Typically, the SWAT model first needs to be calibrated and validated for accurate estimation through adjustment of sensitive input parameters (i.e., Curve Number values, USLE P, slope and slope‐length, and so on). However, in some instances, SWAT‐simulated results are greatly affected by the watershed delineation and Digital Elevation Models (DEM) cell size. In this study, the SWAT ArcView GIS Patch II was developed for steep sloping watersheds, and its performance was evaluated for various threshold values and DEM cell size scenarios when delineating subwatersheds using the SWAT model. The SWAT ArcView GIS Patch II was developed using the ArcView GIS Avenue program and Spatial Analyst libraries. The SWAT ArcView GIS Patch II improves upon the SWAT ArcView GIS Patch I because it reflects the topographic factor in calculating the field slope‐length of Hydrologic Response Units in the SWAT model. The simulated sediment value for 321 subwatersheds (watershed delineation threshold value of 25 ha) is greater than that for 43 subwatersheds (watershed delineation threshold value of 200 ha) by 201% without applying the SWAT ArcView GIS Patch II. However, when the SWAT ArcView GIS Patch II was applied, the difference in simulated sediment yield decreases for the same scenario (i.e., difference in simulated sediment with 321 subwatersheds and 43 subwatersheds) was 12%. The simulated sediment value for DEM cell size of 50 m is greater than that for DEM cell size of 10 m by 19.8% without the SWAT ArcView GIS Patch II. However, the difference becomes smaller (3.4% difference) between 50 and 10 m with the SWAT ArcView GIS Patch II for the DEM scenarios. As shown in this study, the SWAT ArcView GIS Patch II can reduce differences in simulated sediment values for various watershed delineation and DEM cell size scenarios. Without the SWAT ArcView GIS Patch II, variations in the SWAT‐simulated results using various watershed delineation and DEM cell size scenarios could be greater than those from input parameter calibration. Thus, the results obtained in this study show that the SWAT ArcView GIS Patch II should be used when simulating hydrology and sediment yield for steep sloping watersheds (especially if average slope of the subwatershed is >25%) for more accurate simulation of hydrology and sediment using the SWAT model. The SWAT ArcView GIS Patch II is available at http://www.EnvSys.co.kr/~swat for free download.     

Evaluation on the property of sewage sludge cake by thermal treatment

The sewage sludge cake (SSC) used in this study was provided by a K-wastewater treatment plant in Kyonggi-Do, Korea. The characteristics of the SSC, such as particle size, water content, and composition were analyzed. Both the Korea extraction test (KET) and the toxicity characteristic leaching procedure (TCLP) were used to estimate whether the SSC was hazardous. In thermal experiments, the temperature was varied in the range 400° to 900°C and the heating time was varied from 1 to 6 h. The effects of thermal treatment temperature and time were evaluated by turbidity tests on the resultant SSC. On a dry basis, SSC mainly consisted of combustible content (60.2%) and phosphorous (25.9%). The turbidity of SSC was initially estimated in terms of the sedimentation time. The turbidity of SSC decreased exponentially from 9873 FAU at 0 h to 986 FAU at 6 h, so that the sedimentation time of SSC was established as 6 h. From the results of the thermal treatment at 600°C, thermal time can be determined by 2h because the turbidity of SSC is decreased dramatically within 1h and is stabilized after 2h. The turbidity of SSC decreased when the thermal treatment temperature increased from 400° to 900°C. The turbidity after thermal treatment at 400°C for 2 h was 29 FAU and this became almost 10 FAU at 600°C. The SSC was not hazardous, because KET and TCLP analysis produced values that were smaller than the regulatory levels. Hence, it was concluded that SSC can be stabilized by thermal treatment and can be used as a recycled material.     

Environmental quality of Korean coasts as determined by modified Shannon–Wiener evenness proportion

The coast of the Korean peninsula experiences a range of human impacts, including pollution, shipping, reclamation, and aquaculture, that have motivated numerous local studies of macrobenthic organisms. In this paper, 1,492 subtidal stations were compiled from 23 studies (areas) to evaluate environmental quality on a broader scale. A common index in biomonitoring, Shannon–Wiener evenness proportion (SEP), could not incorporate azoic or single-species samples. This shortcoming was overcome by developing an inverse function of SEP (ISEP), which was positively correlated with independent measures of water quality available for nine sites and was not biased by the size of the sampling unit. Additionally, at Shihwa Dike, where samples were collected before and after reinstating a tidal connection with the ocean, ISEP values improved over time, as expected. Thus, it is now possible to assign Korean subtidal sites to seven ISEP “grades” and to use their values and trends to guide coastal management.     

Applying Multi-attribute Utility Theory to Decision Making in Environmental Planning: A Case Study of the Electric Utility in Korea

This paper applies the multi-attribute utility theory (MAUT) to obtaining value judgments concerning the significance of environmental impacts to achieve integration of environmental concerns at an early stage of planning, using the electric utility of Korea as a specific case study. An environmental multi-attribute index is constructed as a multi-attribute utility function, based on value judgments provided by a group of experts related to electric utility and a decision maker from Korea Electric Power Corporation (KEPCO). The societal values are derived from examining trade-offs between environmentalindex and money. The implications of the results for KEPCO are also discussed. We found that the work and results can provide valuable insights and decision opportunities for major decision making in environmental planning facing KEPCO.     

Effects of copper (I) oxide on growth and biochemical compositions of two marine microalgae

In copper based antifouling (AF) paints Cu (I) oxide was largely used as booster biocide. In this study effect of Cu (I) oxide on two marine microalgae, Tetraselmis suecica and Dunaliella tertiolecta was demonstrated. EC50 (96 hr) concentrations estimated for T. suecica and D. tertiolecta were 1.3 mg l(-1) and 1.34 mg l(-1), respectively. Copper (I) oxide induced changes in growth, chlorophyll, carbohydrate and protein contents were observed in T. suecica and D. tertiolecta. At low concentration of 0.0625 mg l(-1), 3-26% and 1-16% growth stimulation was observed in T. suecica and T. tertiolecta respectively. Increasing Cu (I) oxide concentrations proportionately decreased the carbohydrate and protein contents. This study clearly indicates the toxicity of excessive Cu (I) oxide on growth and biochemical compositions of T. suecica and D. tertiolecta.     

Mass Load-Based Pollution Management of the Han River and Its Tributaries, Korea

Spatio-temporal variations of biochemical oxygen demand (BOD) and total coliform (TC) in the Han River, Korea, were investigated in terms of concentration-based and mass loading-based approaches. Considering the river water quality criteria regulated by the Ministry of Environment in Korea, the tributaries linked to the mainstream of the Han River were found to be highly contaminated with respect to both BOD and TC and, in fact, most of the tributaries exceeded the maximum water quality criteria. To evaluate the pollution impact of tributaries on the mainstream, the monthly water quality monitoring data for six years (from 1995 to 2000) were collected from the Han River basin, and statistically analyzed using Pearson’s correlation coefficient. The results revealed that mass loading-based approach was superior to the concentration-based approach for effective Han River watershed management. Overall results supported that the mass loading-based approach associated with total maximum daily loads (TMDL) management would be a useful and suitable protocol in watershed management for improving the water quality of the Han River and protecting public health. Therefore, this study supporting TMDL management can be applicable to a wide array of contaminants and watershed settings in Korea.